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Diverse silver(I) coordination chemistry with cyclic selenourea ligands
(The Royal Society of Chemistry, 2018-01-30)The coordination chemistry of two selenourea ligands (SeIMes and SeIPr) towards silver(I) triflate and silver(I) nitrate was investigated. Two aggregation modes were observed in the solid state, strongly influenced by the ... -
Synthesis and coordination chemistry of cyclic seleno- and telluroureas
(De Gruyter, 2018-07)Chalcogenated derivatives of N-heterocyclic carbene ligands have received increasing attention due to their diverse chemical reactivity and potential applications in fields such as medicine and materials chemistry. ... -
A new polymorph of phenylselenium trichloride
(International Union of Crystallography, 2019-11)A second polymorph of phenylselenium trichloride, PhSeCl3 or C6H5Cl3Se, is disclosed, which is comprised of asymmetric chlorine-bridged noncovalent dimer units rather than polymeric chains. These dimers are each weakly ... -
Crystal structure and computational study of an oxo-bridged bis-titanium(III) complex
(International Union of Crystallography, 2021-06)The solid-state structure of the new compound mu-oxido-bis[dichloridotris(tetrahydrofuran-kappa-O)titanium(III)], [Ti2Cl4O(C4H8O)6], at 150 K has been determined. The crystal has monoclinic (C2/c) symmetry and the complex ...