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Truce–Smiles rearrangement of substituted phenyl ethers
(The Royal Society of Chemistry, 2015-05-26)The requirement of aryl ring activation by strong-electron withdrawing substituents in substrates for the intramolecular nucleophilic aromatic substitution reaction known as the Truce–Smiles rearrangement was examined. ... -
The Truce–Smiles rearrangement and related reactions: a review
(NRC Research Press, 2017-01-16)The Truce–Smiles rearrangement is an X → C aryl migration reaction that is achieved by an intramolecular nucleophilic aromatic substitution pathway. The reaction exhibits a wide substrate scope with respect to a migrating ... -
Effect of the tether length upon Truce‐Smiles rearrangement reactions
(John Wiley & Sons, Ltd., 2017-07-07)This report examines the effect of substrate design upon the Truce‐Smiles rearrangement, an intramolecular nucleophilic aromatic substitution reaction. The length of the molecular spacer that tethers the carbanion nucleophile ...